Triterpenoid Saponins from Stem Bark of Pentaclethra macroloba
نویسندگان
چکیده
Duas novas e duas conhecidas saponinas triterpênicas foram isoladas da casca do caule de Pentaclethra macroloba. As estruturas foram determinadas usando uma combinação de técnicas de RMN homo(1D: RMNH, RMNC-{H}, RMNC-DEPT135; 2D: H-H-COSY, H-HTOCSY, H-H-NOESY) and heteronuclear 2D (HMQC and HMBC), espectros de massas obtidos com ionização por pulverização eletrônica (ESIMS) e métodos químicos. As estruturas das duas novas saponinas triterpênicas foram estabelecidas como 3 -O-{[ -D-glicopiranosil-(1 3)-Lramnopiranosil-(1 2)], -D-glicopiranosil-(1 4)}-L-arabinopiranosilhederagenina (3) e ácido 3 -O-{[ -D-glicopiranosil-(1 4)-D-glicopiranosil-(1 3)-L-ramnopiranosil-(1 2)], -Dglicopiranosil(1 4)}-L-arabinopiranosiloleanólico (4).
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Six new triterpenoid saponins from the root and stem bark of Cephalanthus occidentalis.
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